Clear up initials in XPS

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Aug 6th, 2022
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How to clear up initials in XPS

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these data were acquired as an expanded data set that is to say rather than simply measuring seven spectra from the sample what weamp;#39;ve done is weamp;#39;ve measured many spectra so for each acquisition region we produce a dwell time and required data into different zammis blocks and the advantage of doing that is that you can retrospectively look at your data and examine what actually happened during the course of this experiment in this example a 2d detect has been used to split data spectra over thousands of Valis blocks so this is an example here where itamp;#39;s just temporal the data are split by time and if we look at the initial set of measurements and we sum these we get a spectral form for the C and 3d if we then go to the end of the experiment and again some number of these measurements towards the end of the experiment using this select option then we end up with two different line shapes for this say in 3d that apparently would have all been summed into this one f

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For some materials, plasmon loss peaks may occur. These involve an enhanced probability for loss of a specific amount of energy due to the interaction between the photoelectron and other electrons.
Satellite peaks are used to identify shake-ups, energy loss, plasmons, and other unknown peaks. In the XPS spectrum, these appear as peaks on the high binding energy sides of the primary peak.
In viewing the photoelectron spectrum of an element, you are also able to: Distinguish the different orbital levels in an atom. Determine the electron configuration of an atom. Each peak in a photoelectron spectrum represents a different orbital level where electrons can be found.
Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented.
In XPS analysis, the position of a peak on the x-axis indicates the elemental and chemical composition. This axis is traditionally displayed as Binding Energy in electron volts (eV).
A further source for structure in an XPS spectrum is that of two intrinsic energy loss processes. So called, Shake-up peaks appear at energies characteristic of the excited states for an element with respect to the state measured by the zero loss intensity.
Each element produces a set of characteristic XPS peaks. These peaks correspond to the electron configuration of the electrons within the atoms, e.g., 1s, 2s, 2p, 3s, etc. The number of detected electrons in each peak is directly related to the amount of element within the XPS sampling volume.
Consider the binding energy of an emitted photoelectron, the energy depends on the localised charge of the emitting atom, which itself is determined by the ligands to which it is bound. This is termed an initial state effect, since the electron energies are perturbed before photoionisa- tion.

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