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dear students welcome to epg partshala iamp;#39;m dr raj kishore sharma an associate professor in chemistry department of delhi university today we are going to discuss about the module x-ray photoelectron spectroscopy we will discuss the data analysis part in this this comes under the paper of surface analytical techniques too outline of the topic that we are going to discuss today spin orbital coupling chemical shift then we will discuss multiplet losses plasmon losses quantitative analysis specimen properties sputter yield and age rate will also be discussed we will talk about sample depth sampling deck and sputter profiles now about spin orbital splitting a doublet peak spectrum is observed for p d and f subshells while singlet for s subshell due to the spin orbit coupling after the photoemission of core electron an unpaired electron left behind that has either a parallel or antiparallel orientation antibiotic orientation to the orbital momentum there is an energy differen