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This segment discusses photoemission spectroscopy, focusing on the spectra obtained from the xps instrument. The instrument provides a plot of kinetic energy versus the number of electrons counted, with kinetic energy on the x-axis and number of electrons counted on the y-axis. In modern instruments, kinetic energy is converted to binding energy using a formula, resulting in a shift where lower kinetic energy corresponds to higher binding energy and vice versa. This adjustment changes the starting point of the x-axis from lower to higher binding energy.