Blot out pattern in XPS

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Aug 6th, 2022
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How to blot out pattern in XPS

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hello friends welcome back to the series of photoemission spectra and in this video we will discuss about spin orbital coupling of xps data when we try to analyze the xps data we can see that some of the peaks show sharp single peak like in case of sodium 1s as shown here and in some cases the peak is split into two parts for example as in case of chlorine 2p this peak splitting is observed due to spin orbital coupling as the name suggests it is the coupling or interaction between spin and orbital motion of electron so letamp;#39;s first understand what is spin of electron speed spin is rotation of electron around its own axis and this rotation produces a magnetic field as shown here with the blue line now as electron is also revolving around the nucleus this angular motion also produces a magnetic field we can try to see this orbital motion in an alternate point of view where you can say that the nucleus is moving around the electron itamp;#39;s the same thing but a different perspe

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The blue curve indicates a 5-year derivative. The strength of the XPS technique relies on that the chemical environment of an atom has a pronounced effect on the assessed binding energies (BEs) of core-level electrons, the effect commonly referred to as the chemical shift [2].
Chemical shifts in XPS spectra are observed when an element enters a different bound state, which results in changes in the binding energy of core electrons. In general, increased oxidation state (removal of valence electrons) increases the Binding Energy and addition of valence electrons decreases the Binding Energy.
Here, higher binding energies mean also higher oxidation states. This is known as chemical shift. A good starting point for a literature research for the peak shifts of your material is the XPS database of NIST:
An Auger peak represents the kinetic energy of an auger electron which changes with the energy of primary xrays. Thus, auger peak will shift in apparent binding energy in xps spectrum when x ray source is changed.
The XPS binding energy of an atom is a measure of the electronic environment of the atom. Decreasing the electron density of an atom (such as a C-O bond compared with a C-C bond) increases the binding energy of the atom.
EXPLANATION: If a nucleus has more binding energy, it can hold the nucleus together more strongly which means the nucleus is more stable. So higher the binding energy, the more stable nucleus is.
The more tightly bound a system is, the stronger the forces that hold it together and the greater the energy required to pull it apart.
How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.

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