Bind stain in XPS

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Aug 6th, 2022
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How to bind stain in XPS

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hello my name is jeff schalleberger and iamp;#39;m going to talk to you a little bit about a technique called x-ray photoelectron spectroscopy or xps uh we offer this here in the materials characterization lab at penn state uh you may have also heard the term esca used thatamp;#39;s exactly the same technique it stands for electron spectroscopy for chemical analysis xps is by far the more commonly used terms thatamp;#39;s what iamp;#39;ll use throughout my presentation here xps is based on the photoelectric effect the photoelectric effect is we shine light onto a solid sample and we uh that light in our case in the form of low energy x-rays ejects electrons that were originally bound to the atoms in the material and we knock those electrons off into the vacuum and ultimately measure these with a spectrometer the equation that describes the photoelectric effect is shown here very simple equation this is actually what albert einstein won his nobel prize for in 1921 for some work he d

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For the core-level XPS calculation, we adopted the SCF method with screened core hole pseudopotentials (SCHPs). In the SCF method, the XPS binding energy is obtained as the difference in the total energy between the system where one electron in the relevant core-level is removed and that in the ground state.
The XPS binding energy of an atom is a measure of the electronic environment of the atom. Decreasing the electron density of an atom (such as a C-O bond compared with a C-C bond) increases the binding energy of the atom.
The shifts in the XPS peak is related to its oxidation state and higher shift in binding energy corresponds to higher oxidation state.
In summary, XPS can provide indirect information about the effects of hydrogen bonding on the chemical environment of atoms, but it is not a direct probe of hydrogen bonds themselves.
In equation form, this is given by KEe = hf BE, where KEe is the maximum kinetic energy of the ejected electron, hf is the photons energy, and BE is the binding energy of the electron to the particular material. (BE is sometimes called the work function of the material.)
Knowledge of the incoming photon energy and measurement of the kinetic energy via an electron analyzer makes it possible to calculate the binding energy: Eb = hn + Ek + f, where f is the work function of the spectrometer.
The chemical environment of an atom alters the binding energy (BE) of a photoelectron which results in a change in the measured kinetic energy (KE). The BE is related to the measured photoelectron KE by the simple equation; BE = h - KE where hv is the photon (x-ray) energy.

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