Bind question in XPS in a few clicks

Aug 6th, 2022
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How to bind question in XPS

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so with that Iamp;#39;m gonna introduce Rick hash is actually a senior research scientist at the Materials Research Laboratory here at the U of I he got his feet his batterers degree chemistry from the Marquette University and PhD degree on analytical chemistry from the University of Minnesota or more than 29 years he has of several hundred graduate students and postdocs and senior researchers in the use of XPS in older and he has given numerous invited lectures on XPS and surface and ours techniques to research groups not only at the universe but across around the world he has recently served as in the board of the director of the directors of the American facto suicide AVS and he is currently serving as the editor of the Avs journal surface science spectra SSS so Rick thank you very much for making the time for preparing this presentation and we would like to welcome you so please go ahead okay thanks Mauro for the great introduction ah good afternoon everybody so letamp;#39;s begi

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The chemical environment of an atom alters the binding energy (BE) of a photoelectron which results in a change in the measured kinetic energy (KE). The BE is related to the measured photoelectron KE by the simple equation; BE = h - KE where hv is the photon (x-ray) energy.
In equation form, this is given by KEe = hf BE, where KEe is the maximum kinetic energy of the ejected electron, hf is the photons energy, and BE is the binding energy of the electron to the particular material. (BE is sometimes called the work function of the material.)
The XPS binding energy of an atom is a measure of the electronic environment of the atom. Decreasing the electron density of an atom (such as a C-O bond compared with a C-C bond) increases the binding energy of the atom.
Binding energies of common chemical states: Chemical stateBinding energy C1s C-C 284.8 eV C=C ~284.5 eV C-O ~286 eV C=O 288-290 eV4 more rows
Here, higher binding energies mean also higher oxidation states. This is known as chemical shift. A good starting point for a literature research for the peak shifts of your material is the XPS database of NIST:
Determine the total binding energy (BE) using the equation BE=(m)c2, where m is the mass defect. The binding energy per nucleon (BEN) is BE divided by A (Equation 10.3. 3). BE=[2mp+2mn]m(4He)c2.
The binding energy can be calculated by multiplying the mass lost when the atom or particle is formed by the square of the light in a vacuum. The equation is E=mc2.
An individual photon of EM radiation (it does not come any other way) interacts with an individual electron, supplying enough energy, BE, to break it away, with the remainder going to kinetic energy. The binding energy is BE=hf0 BE = h f 0 , where f0 is the threshold frequency for the particular material.

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