Bind field in XPS

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Aug 6th, 2022
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Cons of XPS: Higher cost compared to EPS. Heavier weight, which can make it more difficult to handle and . Lower R-value per inch of thickness compared to EPS.
Additionally, photoelectron spectroscopy is limited to information about the surfaces of materials, because it is dependent on the dislodged photoelectron traveling from the material to the detector, which grows less likely the more material the electron must travel through.
The XPS binding energy of an atom is a measure of the electronic environment of the atom. Decreasing the electron density of an atom (such as a C-O bond compared with a C-C bond) increases the binding energy of the atom.
The binding energy of a peak tells us how much energy is required to remove an electron from the subshell, and the intensity of the peak tells us the relative number of electrons in the subshell.
X-Ray Photoelectron Spectroscopy is used to determine quantitative atomic composition and chemistry. It is a surface analysis technique with a sampling volume that extends from the surface to a depth of approximately 50-100 .
Both hydrogen and helium cannot be detected using XPS. For this reason, XPS can provide only relative, rather than absolute, ratios of elements in a sample.
Knowledge of the incoming photon energy and measurement of the kinetic energy via an electron analyzer makes it possible to calculate the binding energy: Eb = hn + Ek + f, where f is the work function of the spectrometer.
Because XPS is a surface technique, there is a limited amount of organic information XPS can provide. XPS is limited to measurements of elements having atomic numbers of 3 or greater, making it unable to detect hydrogen or helium. XPS spectra also take a long time to obtain.

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