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all right so now letamp;#39;s talk about that last point about how an xps peak in the spectrum can be shifted due to its local environment or chemistry so this could be viewed as a as a negative in that itamp;#39;s harder to know the exact position of an elementamp;#39;s uh peak but more importantly this actually gives us unique information that other techniques canamp;#39;t and so thatamp;#39;s what xps so along with being surface sensitive xps and also aes give us this local environment of the element and so not only do they give us the composition they give us whatamp;#39;s around it and thatamp;#39;s very important to do with what chemical state itamp;#39;s in and so weamp;#39;ll see some examples of this so this is a chart we tend to see in some of the databases and this is binding energies for uh an element in this case carbon and it you can see the shifts with the different types of compounds so a carbide carbon carbon bonded with nitrogen carbon bonded with sulfur all
