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the XPS of insulators represents a problem that must be solved in that electrons that are emitted from the surface represent negative charges and as a result of having an insulating material I positive charge will build up on the surface and the positive charge attracts the electrons back towards the surface this means that electrons would have a different kinetic energy depending on the charge that has accumulated on the surface Peaks would shift in binding energy in order to measure from an insulating material we have to provide some compensation mechanism where electrons and also potentially positive charge is returned to the surface in order to maintain a balanced charge at the surface during the acquisition of a spectrum now these spectra have been measured using different charge compensation States and you can see simply by looking down this list here that the position for this sulphur 2p peak is changing with each different setting for the charge compensation in order to do an a