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[Music] dear students welcome to EPG part Sala Im dr. Rajesh Sharma an associate professor in chemistry department of Delhi University today we are going to discuss about the module x-ray photoelectron spectroscopy we will discuss the data analysis part in this this comes under the paper of surface and little techniques to outline of the topic that we are going to discuss today spin orbital coupling chemical shift then well discuss multiplet losses plasma losses quantitative analysis specimen properties spreader yield and etch rate will also be discussed well talk about sample depth sampling depth and sputter profiles now about spin orbital splitting a doublet peak spectrum is observed for P D and F sub shells while singlet for s subshell due to the spin orbit coupling after the photo emission of core electron and unpaired electron left behind that has either a parallel or anti-parallel orientation anti piler orientation to the orbital momentum there is an energy difference between