Bind age in XPS

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Aug 6th, 2022
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How to bind age in XPS

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hello everyone today we are going to learn to analyze the xps data using casa xps software this software is can be downloaded free of cost and can be used for the intelligence of xps data so here we are going to analyze the xps data using this particular software here we have the full scan for xps that we can see here it is binding energy versus the intensity of the plots the intensity of the peaks and we can have we are having this data from 0 to a 1300 electron volt okay so we will plot this data in casa xps for this here we will go to convert we will not open it but we will convert it because here in this particular software the data is converted into its own format that is vms format that we can see here we have this full scan weamp;#39;ll open this it will directly get converted if we convert it and if we go back to that particular folder we will have a dot vms file which is the file that is uh of this particular case is software now we need to analyze the peaks that are

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Chemical shifts in XPS spectra are observed when an element enters a different bound state, which results in changes in the binding energy of core electrons. In general, increased oxidation state (removal of valence electrons) increases the Binding Energy and addition of valence electrons decreases the Binding Energy.
The more tightly bound a system is, the stronger the forces that hold it together and the greater the energy required to pull it apart.
The main cause of the peak shift in XPS spectra is mostly related to chemical shifts due to the presence or absence of the chemical states of the element having different formal oxidation state. And the intensity may also be changed bcos it is directly linked to the number of atoms in the respective chemical state.
EXPLANATION: If a nucleus has more binding energy, it can hold the nucleus together more strongly which means the nucleus is more stable. So higher the binding energy, the more stable nucleus is.
Here, higher binding energies mean also higher oxidation states. This is known as chemical shift. A good starting point for a literature research for the peak shifts of your material is the XPS database of NIST:
The XPS binding energy of an atom is a measure of the electronic environment of the atom. Decreasing the electron density of an atom (such as a C-O bond compared with a C-C bond) increases the binding energy of the atom.
The chemical environment of an atom alters the binding energy (BE) of a photoelectron which results in a change in the measured kinetic energy (KE). The BE is related to the measured photoelectron KE by the simple equation; BE = h - KE where hv is the photon (x-ray) energy.

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