Adjust state in XPS smoothly

Aug 6th, 2022
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How to Adjust state in XPS

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hello friends welcome to the second part of the complete series on photoemission spectroscopy in the previous video we have seen the basic principles and instrumentation of xps if you have missed that video you can find the link for the first video in description box now lets talk about the spectra obtained from the xps instrument we have seen that the instrument gives a plot of kinetic energy versus the number of electrons counted so number of electrons counted is plotted in y-axis and kinetic energy is plotted in x-axis so now you can see that it starts from the lower kinetic energy in the left and goes to higher kinetic energy in right as normally a graph is plotted but in most of the modern instruments kinetic energy is converted to binding energy with the formula h nu is equals to binding energy plus kinetic energy plus phi therefore the lower kinetic energy becomes higher binding energy and higher kinetic energy becomes lower binding energy this means now x-axis starts from high

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Hence, the XPS spectrum maps the final states, i.e., energy differences between the ground state of the sample and the numerous final (or ionized) states.
In XPS, the occupation of the 4d orbital of Pd controls the initial state shift offering information about the hybridization of the cluster, while the size and the charging of the cluster controls the final state shift.
Initial state effects describe any effect that results from the electronic structure of an atom/ion undergoing photoelectron emission that was present prior to the photoelectron emission process. These effects are split into two subgroups: Spin-induced interactions present within the photoelectron emitting atom/ion.
When quantifying XPS spectra, Relative Sensitivity Factors (RSF) are used to scale the measured peak areas so that variations in the peak areas are representative of the amount of material in the sample surface. An element library typically contains lists of RSFs for XPS transitions.
Hence, the XPS spectrum maps the final states, i.e., energy differences between the ground state of the sample and the numerous final (or ionized) states.
1] In thermodynamics, an initial state, compared to a final state, refers, generally, to the measurement of the free energy or the reactants, graphically shown on the reaction coordinate, at the start or initial second at the beginning of the reaction sequence.
XPS - Ideal technique for determining oxidation states For the detected elements, energy spectra with high resolution were also acquired in the Tascon laboratory to quantitatively evaluate the existing binding states. The degree of oxidation was determined by evaluating the S2p and Mo3d spectra (see Figure 1a and b).
XPS can measure elemental composition as well as the chemical and electronic state of the atoms within a material. XPS spectra are obtained by irradiating a solid surface with a beam of X-rays and measuring the kinetic energy of electrons that are emitted from the top 1-10 nm of the material.

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