Adjust identification in XPS smoothly

Aug 6th, 2022
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How to Adjust identification in XPS

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hello friends welcome to the second part of the complete series on photoemission spectroscopy in the previous video we have seen the basic principles and instrumentation of xps if you have missed that video you can find the link for the first video in description box now lets talk about the spectra obtained from the xps instrument we have seen that the instrument gives a plot of kinetic energy versus the number of electrons counted so number of electrons counted is plotted in y-axis and kinetic energy is plotted in x-axis so now you can see that it starts from the lower kinetic energy in the left and goes to higher kinetic energy in right as normally a graph is plotted but in most of the modern instruments kinetic energy is converted to binding energy with the formula h nu is equals to binding energy plus kinetic energy plus phi therefore the lower kinetic energy becomes higher binding energy and higher kinetic energy becomes lower binding energy this means now x-axis starts from high

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Shake-up satellites: distinct peaks a few eV below the main line. Shake-off satellites: broad feature at lower energy w.r.t. to main line. energy loss). n: e density, e: charge of e, m: mass of e electron.
XPS is surface sensitive due to the short inelastic mean free path, , of electrons in Condensed materials. Typical values are 12 nm for metals, 1.54 nm for oxides and down to 3 nm for organic materials.
Limitations of Photoelectron Spectroscopy Valence electrons⁠those involved in chemical bonds⁠can be dislodged with ultraviolet photons, but core electrons require the energies of X-ray photons.
An accuracy of 10% is typically quoted for routinely performed XPS atomic concentrations. For specific carefully performed and characterised measurements better accuracy is possible, but for quantification based on standard relative sensitivity factors, precision is achieved not accuracy.
Hydrogen has no core electrons and, therefore, coreelectron XPS is impossible. The H 1s electrons are valence electrons and as such participate in chemical bonding. Any signal from hydrogen would overlap with signals from excitation of valence electrons from other surface atoms.
How to Analyze XPS Spectra Data The X-Axis: Peak Position. The Y-Axis: Peak Intensity. Overlapping Peaks. More than One Elemental Peak. Analysis of Haze on a Polyimide Substrate. Passivation Integrity of Stainless Steel.
Detection limit is ~0.05-0.1 atomic % for most elements.
Hydrogen has no core electrons and, therefore, coreelectron XPS is impossible. The H 1s electrons are valence electrons and as such participate in chemical bonding. Any signal from hydrogen would overlap with signals from excitation of valence electrons from other surface atoms.

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