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The video discusses the importance of background algorithms in analyzing photo emission spectra. An elastic Li scattered background is associated with electrons moving through a solid state, causing peaks to represent electrons of a kinetic energy that may be scattered and lose energy. This results in a background signal from not just 4f electrons, but also 5p and valence band electrons. Removing this background is essential for accurate analysis of the gold 4d doublet at a lower kinetic energy. Additionally, not all 4d electrons will leave the surface and be recorded at the characteristic energy of the gold.