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in this video were going to look at the surely background algorithm and the reason that you need a background algorithm is because a photo emission spectrum includes an elastic Li scattered background that is associated with electrons moving through a solid state with a given energy so these photo emission Peaks represent electrons of a given kinetic energy but when these electrons move through the solid state they are scattered and lose energy and therefore the signal that should be here at the gold for F appear at energies to lower kinetic energy than the peak itself and this background will be a result of not just these 4f electrons but these 5p and the valence band as well so these all represent a source for this background signal that must be removed from a gold 4d doublet that is at a lower kinetic energy now in addition when the gold 4d electrons appear these two are scattered so not all 4d electrons will leave the surface and be recorded at the characteristic energy of the go