Adapt trace in XPS smoothly

Aug 6th, 2022
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How to Adapt trace in XPS

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Charles Zona (CZ): Hello, and welcome to another McCrone Group webinar. My name is Charles Zona, and today we are happy to welcome Doug Meier. Doug is going to talk to us about X-ray photoelectron spectroscopy, otherwise known as XPS. Before we get started I would like to give you a bit of Dougs background. Doug is a senior research scientist with McCrone Associates. He specializes in surface sensitive spectroscopies, such as Auger electron, X-ray photoelectron, infrared reflection absorption, thermal desorption, and low-energy electron diffraction. Doug was awarded the U.S. Department of Commerces Silver Medal for his work in the development of conductometric chemical microsensor array technology for the detection of chemical warfare agents. He also has over ten years of micro beam analysis experience prior to joining McCrone Associates. Doug will field questions from the audience immediately following todays presentation, and this webinar is being recorded and will be available on

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XPS spectra are obtained by irradiating a solid surface with a beam of X-rays and measuring the kinetic energy of electrons that are emitted from the top 1-10 nm of the material. A photoelectron spectrum is recorded by counting ejected electrons over a range of kinetic energies.
The greater the binding energy, the greater the attraction of that electron to the nucleus. i.e. peaks from electrons in 1s will have a greater energy than peaks representing electrons from 2s. Electrons in 2s will have greater energy than those in 2p.
In XPS, the atoms of the samples surface absorb X-rays and emit electrons, but in XRF the atoms of the sample both absorb and emit X-rays.
Explanation: Electron multiplier is the most commonly used detectors in ESCA and AES.
In XPS instruments, X-rays are generated by bombarding a metallic anode with high-energy electrons. The energy of the emitted X-rays depends on the anode material and beam intensity depends on the electron current striking the anode and its energy.
Hydrogen and helium are essentially impossible to detect by a lab-based XPS. Helium is not normally present as a solid and even when present (implanted) in a solid its 1s orbital has a very small cross-section for photoemission.
The most prevalent electron spectrometer for XPS is the hemispherical electron analyzer. They have high energy resolution and spatial selection of the emitted electrons.
The main difference is that XPS uses an X-ray beam to eject an electron while AES uses an electron beam to eject an electron. In AES, the sample depth is dependent on the escape energy of the electrons.

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