Vary feature in XPS smoothly

Aug 6th, 2022
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How to Vary feature in XPS

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hello my name is jeff schalleberger and im going to talk to you a little bit about a technique called x-ray photoelectron spectroscopy or xps uh we offer this here in the materials characterization lab at penn state uh you may have also heard the term esca used thats exactly the same technique it stands for electron spectroscopy for chemical analysis xps is by far the more commonly used terms thats what ill use throughout my presentation here xps is based on the photoelectric effect the photoelectric effect is we shine light onto a solid sample and we uh that light in our case in the form of low energy x-rays ejects electrons that were originally bound to the atoms in the material and we knock those electrons off into the vacuum and ultimately measure these with a spectrometer the equation that describes the photoelectric effect is shown here very simple equation this is actually what albert einstein won his nobel prize for in 1921 for some work he did explaining this effect in 190

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The XPS spectrum contains peaks at 285.03 eV attributed to the binding energy of C1s, 103.29 eV to the binding energy of Si2p, 83.98 and 87.7 eV to the binding energy of Au4f7/2 and Au4f5/2, respectively, and 532.68 eV to the binding energy of O1s.
The perturbation is called shake-up if they refer to an excitation in the final system, or shake-off if the result is the loss of one or more outer shell electrons from the ion.
The most prevalent electron spectrometer for XPS is the hemispherical electron analyzer. They have high energy resolution and spatial selection of the emitted electrons.
XPS can measure elemental composition as well as the chemical and electronic state of the atoms within a material. XPS spectra are obtained by irradiating a solid surface with a beam of X-rays and measuring the kinetic energy of electrons that are emitted from the top 1-10 nm of the material.
Shake-up satellites: distinct peaks a few eV below the main line. Shake-off satellites: broad feature at lower energy w.r.t. to main line. energy loss). n: e density, e: charge of e, m: mass of e electron.
Basic principles of XPS Why is this a surface technique? So the excited photoelectrons are relatively slow and mostly interact with the material they are generated and lose energy. A few electrons get out un-scattered and are detected as the photoelectron peaks. (mostly from the upper 10 nm of the material.)
How XPS works. X-rays (photons) are shot onto a sample, and when electrons in the sample absorb enough energy, they are ejected from the sample with a certain kinetic energy. The energy of those ejected electrons is analyzed by a detector and a plot of these energies and relative numbers of electrons is produced.
Satellite Peaks One of the advantages in using monochromatic X-rays is that the distribution of the photon energies used in the analysis is narrow compared to the unfiltered X-ray line and therefore improves the resolution of the photoelectric peaks in the XPS spectrum.
The main components of an XPS system are the source of X-rays, an ultra-high vacuum (UHV) chamber with mu-metal magnetic shielding, an electron collection lens, an electron energy analyzer, an electron detector system, a sample introduction chamber, sample mounts, a sample stage with the ability to heat or cool the

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