Fill in guide in XPS in a few clicks

Aug 6th, 2022
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How to fill in guide in XPS

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hello my name is jeff schalleberger and iamp;#39;m going to talk to you a little bit about a technique called x-ray photoelectron spectroscopy or xps uh we offer this here in the materials characterization lab at penn state uh you may have also heard the term esca used thatamp;#39;s exactly the same technique it stands for electron spectroscopy for chemical analysis xps is by far the more commonly used terms thatamp;#39;s what iamp;#39;ll use throughout my presentation here xps is based on the photoelectric effect the photoelectric effect is we shine light onto a solid sample and we uh that light in our case in the form of low energy x-rays ejects electrons that were originally bound to the atoms in the material and we knock those electrons off into the vacuum and ultimately measure these with a spectrometer the equation that describes the photoelectric effect is shown here very simple equation this is actually what albert einstein won his nobel prize for in 1921 for some work he d

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The XPS (X-ray Photoelectron Spectroscopy) is one of the typical non-destructive analyzing methods.
XPS Sample Preparation: Press the powder into clean, high purity indium foil. Dissolve the powder in a suitable solvent and then drop cast onto the surface of a clean silicon wafer. Sprinkle the powder onto the surface of sticky carbon conductive tape or pressed into a tablet for analysis.
Because XPS is a surface technique, there is a limited amount of organic information XPS can provide. XPS is limited to measurements of elements having atomic numbers of 3 or greater, making it unable to detect hydrogen or helium. XPS spectra also take a long time to obtain.
XPS measurements are conducted under ultra-high vacuum ( 10- 8 Torr) in order to avoid collision between photoelectrons and gas molecules in the spectrometer, and minimize surface contamination from residual gases.
How to interpret the data it generates Peaks from the XPS spectra give relative number of electrons with a specific binding energy. The shorter the peak, the less electrons represented. The greater the binding energy, the greater the attraction of that electron to the nucleus.
XPS can detect submonolayer coverages, so proper sample handling is essential. As mentioned above, gloves should be worn and clean metal tweezers used to handle the sample without contacting the area of interest.
The average depth of analysis for an XPS measurement is approximately 5 nm. PHI XPS instruments provide the ability to obtain spectra with a lateral spatial resolution as small as 7.5 m. Spatial distribution information can be obtained by scanning the micro focused x-ray beam across the sample surface.
X-ray Photoelectron Spectroscopy (XPS) or Electron Spectroscopy for Chemical Analysis (ESCA) is a technique which analyzes the elements constituting the sample surface, its composition, and chemical bonding state by irradiating x-rays on the sample surface, and measuring the kinetic energy of the photoelectrons emitted

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