Clean character in XPS smoothly

Aug 6th, 2022
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How to Clean character in XPS

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this video is an introduction to xps xps is most often viewed through the analysis of xps data which involves using software to work out quantification and chemical state information based on spectra that are gathered from samples but to properly understand how the sample is analyzed in terms of the software its important to have some appreciation of the xps technique itself so this involves having an understanding of what were looking at in terms of energy spectra and also how spectra are acquired that will then be processed to produce the information that were after an xps spectrum is an energy spectrum and the energy spectrum is acquired by changing the energy at which we sample the number of electrons that arrive at a detector and as a consequence of these types of measurements we can create a histogram of intensity as a function of energy here its plotted as intensity as a function of binding energy and the binding energy is related to an electronic configuration with an atom

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XPS is used to characterize the surfaces of diverse materials such as inorganic compounds (minerals), semiconductors, organic compounds, and thin films and coatings on natural and engineered materials.
Shake-up satellites: distinct peaks a few eV below the main line. Shake-off satellites: broad feature at lower energy w.r.t. to main line. energy loss). n: e density, e: charge of e, m: mass of e electron.
Basic principles of XPS Why is this a surface technique? So the excited photoelectrons are relatively slow and mostly interact with the material they are generated and lose energy. A few electrons get out un-scattered and are detected as the photoelectron peaks. (mostly from the upper 10 nm of the material.)
The variation of binding energy results in the shift of the corresponding XPS peak, ranging from 0.1eV to 10eV. This effect is termed as chemical shift, which can be applied to studying the chemical status of element in the surface. Therefore, XPS is also known as electron spectroscopy for chemical analysis (ESCA).
Curve/peak fitting is often the only way to extract quantitative information from these spectra. The objective of curve-fitting high-resolution core XPS spectra with a set of component peaks is to separate the photoemission signal originating from distinct elemental or chemical states.
Photoelectric Peaks, Auger Peaks and Energy Scales.
The most prevalent electron spectrometer for XPS is the hemispherical electron analyzer. They have high energy resolution and spatial selection of the emitted electrons.
The perturbation is called shake-up if they refer to an excitation in the final system, or shake-off if the result is the loss of one or more outer shell electrons from the ion.

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