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were going to go through the fitting of the titanium 2p peak this is a sample of titanium apatite composite and as you can see theres a number of different oxidation states that are present this is a good example for the transition metals it shows a number of things we have gonna have an asymmetric peak for the metal we have spin-orbit splitting going on and so we may have to deal with multiple it splitting for some of the states and so were gonna go through those things this sample has already been charged corrected to 2 carbon 1 s set to 2 84.8 evie for adventitious carbon so were already done that the first thing were going to do is create a background region go to components and we want to start adding in and sub components so the first thing were going to put in is the spin-orbit doublets for the metallic peak so lets add two peaks and well just slide them around so that we theyre more where they should be and were going to talk a little bit about what we need to do to