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these spectra were measured from a oxide in a faultless State the 3d spectra as shown here indicate that we have more Peaks than youd expect for a molybdenum 4 plus state and we have model DS using for the 4 plus state the peak structure that was suggested by Scanlon at Hal that is to say that the four per state is constructed from two sets of doublet pairs and these represent screened and unscreened electrons are associated with unpaired electrons in the four plus state whereas in the six plus state we have a doublet pair where the line shapes are symmetrical are far simpler in structure than in the four plus state and the idea of this measurement was to observe how the envelope generated by just repeatedly measuring the same sample would change as a consequence of the acquisition itself we would like to is illustrate how the six plus state does change as a consequence of repeated measurement the four plus state however is a far more stable and does not show any docHub changes